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Synthesis 2004(9): 1413-1418
DOI: 10.1055/s-2004-822376
DOI: 10.1055/s-2004-822376
PAPER
© Georg Thieme Verlag Stuttgart · New YorkC-C Bond Formation via N-Phosphoryliminium Ions
Further Information
Received
15 April 2004
Publication Date:
18 May 2004 (online)
Publication History
Publication Date:
18 May 2004 (online)
Abstract
This paper describes preliminary results in the field of rather unexplored nucleophilic additions to N-phosphoryliminium ions. The synthesis of allylic and non-allylic cyclic amidophosphate-based N,O-acetals and their application in C-C bond formation is detailed. In addition, the influence of a chiral auxiliary on the phosphorus atom has been investigated.
Key words
amidophosphate - phosphoryliminium ion - N,O-acetal - ring-closing metathesis - alkoxyallene
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